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Bo Jönsson

Professor emeritus

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The effect of polycations on early cement paste

Author

  • I. Pochard
  • C. Labbez
  • A. Nonat
  • H. Vija
  • Bo Jönsson

Summary, in English

This paper studies the possibility for improving the ductility of cement based materials by means of oligocationic additives. Actually, the setting of cement is due to ionic correlation forces between highly negatively charged C-S-H nanoparticles throughout a calcium rich solution. The main drawback of this strong attraction is its very short range that results in low elastic deformation of hydrated cementitious materials. A way to enlarge the attraction range between C-S-H particles would be to add cationic oligomers that would compete with calcium ions modifying the ionic correlation forces via a bridging mechanism of longer range, which could lead to a more ductile material. The studied parameters were the polymerization degree, the separation distance between the charged monomers and the balance between oligocations and monovalent and divalent cations in the solution. The results, both experimental and numerical by Monte Carlo (MC) simulations, demonstrate that cationic oligomers can compete with calcium cations as counterions to the C-S-H surface. The cohesive forces between C-S-H surfaces, calculated by MC simulations, show an interesting behaviour where range and, magnitude can be tuned with oligomer concentration, polymerization degree and line charge density. Thus, it seems possible to modulate the ductility and critical strain of cement by addition of cationic oligomers. (C) 2010 Elsevier Ltd. All rights reserved.

Department/s

  • Computational Chemistry
  • eSSENCE: The e-Science Collaboration

Publishing year

2010

Language

English

Pages

1488-1494

Publication/Series

Cement and Concrete Research

Volume

40

Issue

10

Document type

Journal article

Publisher

Elsevier

Topic

  • Theoretical Chemistry (including Computational Chemistry)

Keywords

  • Bridging force
  • Tensile properties
  • Cement paste
  • Polymers

Status

Published

ISBN/ISSN/Other

  • ISSN: 0008-8846