Gunnar Karlström
Professor emeritus
On the effective interaction between an ion and a hydrophobic particle in polar solvents. A step towards an understanding of the hofmeister effect?
Author
Summary, in English
It has been shown that the generally accepted assumption that hydrophobic molecules and ions repel each other in polar solvents is only valid for moderately polar solvents. When the dipole moment of the medium molecules is increased, then ions and hydrophobic particles start to attract each other. For particles with the size and dipole moment of a water molecule one can expect that the effective potential curve between the two types of particles is almost flat. This opens up for an explanation of the 114 years old unexplained Hofmeister effect.
Department/s
- Computational Chemistry
Publishing year
2003
Language
English
Pages
3238-3246
Publication/Series
Physical Chemistry Chemical Physics
Volume
5
Issue
15
Document type
Article
Publisher
Royal Society of Chemistry
Topic
- Theoretical Chemistry (including Computational Chemistry)
Status
Published
ISBN/ISSN/Other
- ISSN: 1463-9084